Materials Kinetics: Transport and Rate Phenomena provides readers with a clear understanding of how physical-chemical principles are applied to fundamental kinetic processes, covering the full spectrum of materials science and engineering. It integrates advanced concepts with foundational knowledge and cutting-edge computational approaches, demonstrating how diffusion, morphological evolution, viscosity, relaxation, and other kinetic phenomena can be applied to practical materials design problems across all classes of materials. The book starts with an overview of thermodynamics, discussing equilibrium, entropy, and irreversible processes. The subsequent chapters focus on analytical and numerical solutions of the diffusion equation, covering Fick's laws, multicomponent diffusion, numerical solutions, atomic models, and diffusion in crystals, polymers, glasses, and polycrystalline materials. Dislocation and interfacial motion, kinetics of phase separation, viscosity, and advanced nucleation theories are examined next, followed by detailed analyses of glass transition and relaxation behavior. The book concludes with a series of chapters covering molecular dynamics, energy landscapes, broken ergodicity, chemical reaction kinetics, thermal and electrical conductivities, and Monte Carlo simulation techniques, and master equations. Real-world applications are provided throughout, and each chapter ends with a set of practical exercises to reinforce the lessons and concepts previously covered.
Materials Kinetics : Transport and Rate Phenomena